Thermodynamic Modeling of Iron-Copper-Sulfuric Acid

Solvent extraction and electrowinning (SX/EW) play an important role during the hydrometallurgical production of copper for low-grade ores. To better understand the rapid Cu extraction/strip kinetics for producing a high-purity CuSO 4 –H 2 SO 4 electrolyte and elucidate the method to maximize current efficiency by preventing leach carryover to electrolyte during …

Innovations: How Hydrometallurgy and the SX/EW …

The SX/EW process has provided the copper industry with a tool that makes the extraction of copper from its ores significantly more environmentally friendly than by the use of the conventional smelting process.

The FL ROL Process: BASF-FLS Pilot Plant …

Various mechano-chemical leach/SX flowsheet configurations can be considered for copper sulfide treatment systems. Firstly, there is the choice of intra- versus inter-stage placement of the stirred

Current status and limitations of copper SX/EW plants …

Because of the abundance of heterogeneous copper sulfide, the solvent extraction is subjected to great operational challenges, which might compromise the plant effectiveness of the hydrometallurgy ...

Improved Copper/Iron Selectivity in Solvent Extraction

to a secondary sulfide zone, containing enriched copper species such as covelite (CuS) and chalcocite (Cu 2 S). The secondary sulfide zone represents approximately 25 % of the total copper. The rest of the ... information from a pilot-plant trial run at a commercial SX plant that uses both modified and non-modified hydroxyoximes. 283

Copper Heap Leaching & SX-EW Slideshow

In the SX-EW plant, the copper-bearing acid solution from the collection pond is mixed with water and an organic solvent that preferentially binds to the copper ions. This mixture is allowed to settle and separate. The organic copper-rich portion floats to the top, and the metal-free portion falls to the bottom. This step is called

Copper leaching from primary sulfides: Options for …

The sulfate-based processes involve copper leaching, solid–liquid separation and residue washing, copper SX/EW and raffinate management. The raffinate management can …

The FL ® ROL Process: BASF-FLS Pilot Plant Testing

The copper mining industry faces two significant challenges: 1) economic stress during the transition from oxide to sulfide ores, and 2) high smelting costs and environmental issues in treating ...

Zinc and Lead Solvent Extraction and Electrowinning

SX is common for treating complex, low-grade electrolytes for separation, purification, enrichment, and recovery. SX plants are closed loop in concert with leaching and EW with optimum recycling of reagents to produce metal cathode. SX can also be used to extract and separate Ni and Co from chloride, ammoniacal, and sulphate solutions.

Innovations: How Hydrometallurgy and the SX/EW Process Made Copper …

These may be mined copper minerals that are in oxidized form - minerals such as Azurite (2CuCO 3 · Cu(OH)3), Brochantite (CuSO 4), Chrysocolla (CuSiO 3 · 2H 2 O) and Cuprite (Cu2O), residual copper in old mine waste dumps whose sulfide minerals have been oxidized by exposure to the air or sulfididic copper minerals that have been oxidized by ...

Medium-temperature pressure leaching of copper …

A comprehensive pilot plant program was developed for the Morenci application with the following objectives: • determine the process-design criteria, including preferred operating conditions, for the MT-DEW-SX process at Morenci with three different copper sulfide mineral blends (although partially composed of flotation concentrates

Development of SX-EW Process for Copper Recovery—An …

This paper reviews the progress made to date for processing copper oxide and sulfide ores through the application of Solvent Extraction-Electrowinning (SX-EW) process …

Development of SX-EW Process for Copper …

This paper reviews the progress made to date for processing copper oxide and sulfide ores through the application of Solvent Extraction-Electrowinning (SX-EW) process technology. SX-EW Kchnology is a two step …

Copper Solvent Extraction

Leaching copper from oxide ores, low grade secondary sulfide ores, and primary sulfide concentrates with aqueous acid or ammonia solutions, followed by solvent extraction ... final copper product Commercial copper SX plants are designed around one of the several proven circuit configurations: series, series parallel,

HYDROMETALLURGY AT THE SUNSHINE MINE …

SX Plant Parameters. Conventional NSC plant. Feed Cu: 2-8 g/l 8-10 g/l. ... The presence of soluble copper prevents the formation of the hydrogen sulfide by the formation of copper sulfide, and ...

Innovations: Phelps Dodge Morenci Has Converted All Copper …

The new "mine-for-leach" process uses bacteria to extract copper from the ore and solvent extraction/electrowinning (SX/EW) to recover copper from the resulting leach liquor. Phelps Dodge has ceased all recovery of copper from sulfide mineral concentrates by means of conventional smelting operations at its Morenci, Arizona operations.

Obtention of Suitable Pregnant Leach Solution (PLS) for Copper …

Copper leaching presents an environmentally friendly alternative to traditional sulfide ore processing methods. This study investigates an efficient leaching process for copper concentrate, utilizing a solution of sulfuric acid (H2SO4) and potassium iodide (KI) in a chloride medium (NaCl), enhanced by hydrogen peroxide (H2O2) at room temperature. A significant …

Copper leaching from primary sulfides: Options …

The process uses low temperature pressure oxidation to directly leach copper from the ore followed by SX/ EW of copper from the resulting leach solution. The plant operation achieved an annualized copper production of 50,000 tonnes …

Pre feasibility study in hydrometallurgical treatment of …

Ores tested included low-grade sulfide ore with copper sulfide minerals including chalcocite, covellite and chalcopyrite, as well as oxide and mixed oxide/sulphide ores. ... Operating cost for the bio heap/SX/EW plant with 7000 copper cathode/year capacity form a low grade (0.28% Cu) chalcopyrite ore (open pit mining cost included). All prices ...

A fresh approach to sulfide ores

To make the transition from oxides to sulfides as seamless and economical as possible, it benefits copper miners to invest in copper sulfide extraction processes that integrate and maximize production from existing solvent-extraction and electrowinning (SX/EW) infrastructure, according to Gary Roy, director for FL's rapid oxidative ...

Copper Solvent Extraction: Status, Operating Practices …

Operating copper SX–EW plants and near-term projects in the Copper Belt. COPPER SX: A TRULY ADAPTABLE PROCESS Distinct characteristics emerge when one examines copper …

Copper Bioleaching Operations in Chile: Towards New

By 2012, bioleaching became the standard method for low-grade copper sulfide processing, allowing processing of copper feed grades as low as 0.4%. ... In addition, the depletion of copper oxides has generated surplus capacity at SX-EW plants, which leads to an opportunity for the processing of complex and low-grade sulfide minerals through ...

SX-EW Moves into New Metal Markets

SX-EW has continued to demonstrate successful use in effectively extracting and recovering copper from low grade and oxide ores. As a result, SX-EW has quickly become a staple in the copper industry; SX-EW is currently responsible for producing around 20% of the world's copper (see the infographic on copper production). This demonstrated ...

Copper leaching from primary sulfides: Options for …

In selected cases, copper heap leach-SX/EW process plants are running out of ore feed. These plants have fully functional SX/EW plants available for further copper recovery as electrowon cathode. In this case, it may make sense to adopt a copper concentrate hydrometallurgy process as the "front end" of the process plant and further utilize ...

Technology – BioCopper

Leaching technology for sulfur mineral concentrates in Heap-type reactors, developed and marketed by LIAP.; It uses a plastic matrix as an agglomeration core, allowing the hydrometallurgical recovery of the contained values.; Feasibility of using idle Lix-SX-EW plant capabilities.; Feasible to be applied by various biological and/or chemical oxidizing agents.

Implementation and practice of an integrated process to recover copper

The HBL-SX-EW plant was refurbished in 2011 and started up in 2012. The second and third concentrator plants were commissioned, respectively, in 2012 and 2016. ... SX-EW and copper sulfide precipitation. In the process, copper and valuable metals are efficiently recovered. The objectives of comprehensive utilization of resources and ...

Industrial practice of a distinct bioleaching system operated …

This paper discusses a case study on a bioheapleaching system operated commercially at Zijinshan copper plant in China, which applied bioheapleaching–SX (solvent extraction)–EW (electrowinning) to treat a distinct secondary copper sulfide ores. ... presented in this paper provides operational data and analysis that would benefit the ...

Biocopper tech

It allows the clean process of flotation sulfide concentrates with impurities (arsenic, cadmium, and others). Lower environmental impact than alternative smelting and refining. It generates copper-laden solutions to feed SX-EW plants directly. It allows for to develop of circular economy action plans for plastic waste.

Morenci Mine

Processes and facilities: The Morenci operation includes a 50,000 mtd concentrator that produces copper and molybdenum concentrates; a 68,000 mtd crushed-ore leach pad and stacking system; a low-grade run-of-mine leaching system; four solution extract (SX) plants; and three electrowinning (EW) tank houses that produce copper cathode. Morenci also has a …

Chemical Processing: Hydrometallurgy | SpringerLink

Over 20 % of the global output of refined copper is produced by solvent extraction-electrowinning (SX-EW) hydrometallurgical plants and is generally suited for low-grade ores. The SX-EW process is superior to other processes such as cementation of copper in terms of improved product quality and costs.